The actress, 48, stepped out Tuesday with son Pax, 20, daughter Zahara, 18, and son Knox, 15.
Jolie is also mom to son Maddox, 22, daughter Shiloh, 17, and daughter Vivienne, Knox’s twin, all of whom she shares with her ex-husband Brad Pitt.
For the family outing, Jolie went with an all-black ensemble, opting for an oversized blazer and matching slacks, which she paired with closed-toe pumps, sunglasses, a quilted leather tote and a variety of dainty bracelets.
The brunette beauty let her ombré locks cascade down her shoulders, and she appeared to sport little-to-no makeup as she flashed a big grin.
Pax, for his part, kept things cool with black Converse sneakers, gray pants, a white T-shirt beneath a flannel and a black beanie.
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Pax — whom Page Six exclusively reported in January was secretly an artist working in “digital and mixed media” under the pseudonym Embtto — accessorized his look with a camera around his neck and several large bags in tow.
Meanwhile, Zahara — who is a student at Spelman College in Atlanta — donned a navy blue quilted puffer jacket atop a white shirt, black pants, navy blue Converse sneakers, a small clutch and her phone in her hand.
Knox — who’s rarely photographed in public — wore a casual navy blue hoodie, olive green cargo pants and white Nike kicks.
Jolie’s NoHo shop — which used to be the home and studio of Andy Warhol contemporary Jean-Michel Basquiat — will sell both Atelier Jolie pieces and those created by other labels in the sustainable fashion space.
The location will also include a café “run by refugee and immigrant chefs” as well as a gallery, and it will host various classes “focused on techniques such as silk-screening, studding and embroidery.”
As for her relationship with her kids, Jolie recently called them her best pals.
“They are the closest people to me and my life, and they’re my close friends,” she told WSJ Magazine earlier this month.
“We’re seven very different people, which is our strength,” she continued, adding that they all “had to heal” following her tumultuous divorce from their father, 60.